Distilleries produce large amounts of organic waste, particularly raw spent wash, which can be a challenge to treat. The CSTR system offers a robust solution for the anaerobic treatment of this waste, converting organic materials into biogas and significantly reducing the pollution load. This process is ideal for distilleries as it not only reduces the environmental impact but also recycles energy in the form of biogas, which can be used for heating or electricity generation.
Terminology Used in Digester (Biomethanation)
Chemical Oxygen Demand (COD)
COD is a critical parameter that indicates the amount of oxygen required to oxidize organic compounds in the wastewater. In the context of anaerobic digestion, a high COD value signifies a high concentration of organic pollutants, which the CSTR system can break down effectively to generate biogas.
Biological Oxygen Demand (BOD)
BOD measures the amount of oxygen required by microorganisms to degrade organic matter in water. A high BOD level indicates a high concentration of biodegradable material, making it a good candidate for anaerobic treatment processes like CSTR.
Total Solids
Total solids include both suspended and dissolved solids present in the wastewater. The CSTR system is designed to handle high concentrations of solids, converting organic materials into biogas while separating and concentrating inorganic solids as residue.
Anaerobic Digester
An anaerobic digester is a sealed, oxygen-free environment where organic matter is broken down by anaerobic microorganisms. The CSTR digester is a highly efficient form of anaerobic digester, ensuring optimal biomass-waste interaction and maximizing biogas production.
Acetogenic Bacteria
Acetogenic bacteria play a key role in the anaerobic digestion process by converting volatile fatty acids into acetic acid, a precursor to methane production. Their activity is essential in the conversion of organic material into biogas.
Methanogenic Bacteria
Methanogenic bacteria are responsible for the final step of anaerobic digestion, converting acetic acid and other organic compounds into methane, which forms the majority of the biogas produced by the CSTR system.
Biogas
Biogas is the main product of the anaerobic digestion process, consisting mainly of methane (CH4) and carbon dioxide (CO2). It is an energy-rich gas that can be used for electricity generation or as a fuel for heating purposes, making the CSTR system an attractive solution for waste-to-energy applications.
Description Of Anaerobic Digester
CSTR Digester consist of continuous stirred tank reactor where continuous mixing of effluent and biomass take place with the help of central and lateral agitators. Wastewater or sludge is fed into the digester, and microorganisms break down the organic material over time, producing biogas as a byproduct. The reactor includes a recycle loop, ensuring that biomass remains in constant contact with the waste for optimal conversion to biogas.
Basic Reactions in the CSTR System
Reaction:
1. Hydrolysis: Organic material is broken down into simpler compounds such as sugars and amino acids by hydrolytic bacteria.
2. Acidogenesis: Acetogenic bacteria convert the simpler compounds into volatile fatty acids (VFAs), hydrogen, and carbon dioxide.
3. Acetogenesis: Acetogenic bacteria further break down VFAs into acetic acid.
4. Methanogenesis: Methanogenic bacteria convert acetic acid and hydrogen into methane (CH4) and carbon dioxide (CO2).
Parameter of CSTR Digester
Several parameters influence the performance of a CSTR system. These include temperature, pH, hydraulic retention time (HRT), organic loading rate (OLR), and mixing efficiency. Maintaining these parameters within optimal ranges ensures maximum biogas production and efficient treatment of waste.
CSTR / Digester Process
The process begins with the feeding of raw organic waste, such as spent wash, into the CSTR digester. The waste is continuously mixed to ensure consistent contact with biomass. As microorganisms break down the organic material, biogas is produced. The treated waste is then discharged, typically after a sufficient retention time, while the biogas can be harvested for use.
Design Criteria of the CSTR System (Anaerobic Digester)
Calculation of Biogas Generation
Biogas production is influenced by the chemical composition of the feedstock, particularly the COD and BOD levels. The amount of biogas produced can be estimated using the stoichiometric relationship between COD and biogas yield. On average, 1 kg of COD can produce approximately 0.35-0.45 m3 of biogas under optimal conditions.
Volume of the CSTR Digester
The volume of the CSTR digester is determined based on the organic loading rate (OLR) and the desired hydraulic retention time (HRT). The HRT is typically between 15-30 days for wastewater treatment, while the OLR depends on the characteristics of the feedstock. The volume is designed to ensure sufficient time for complete digestion, optimal biogas production, and effective treatment of waste.